He soon drinks, and narrowly escapes cardiac arrest. So Valenka does the job, she is standing by the drinks cabinet when she slips Digitalis Poison into 007's martini. For instance, when Bond is winning, Le Chiffre declares he wants Bond poisoned. Nonetheless, Valenka stays with Le Chiffre and despite all this is still carrying out orders from him.

He tells her that she should find a new boyfriend before he and his boyfriend release her and leave. Stating he has been betrayed, Obanno moves in, but seeing no protest from Le Chiffre, Obanno halts from cutting off Valenka's arms mere inches from it. Holding Valenka, Obanno threatens to slice off her arm, saying Le Chiffre needs his hand to play cards. She is suddenly grabbed from behind by Steven Obanno and his liaison, who grab Valenka and Le Chiffre and throw them into their hotel room. She is in her hotel room one night in the stay when she is standing guard for Le Chiffre, and she is berated by Le Chiffre for her annoying him, but then she kisses him to calm him down, showing her affection for him. Later, Valenka is seen during the progressing tournament. Valenka is later seen at the Casino Royale, where she is with Kratt, and she stands against railings and watches Le Chiffre play against 007, and Valenka talks to Kratt as her boyfriend plays.

One of Le Chiffre's friends is eyeing her, and Le Chiffre is prompted to challenge him to another bet. She then goes voluptuously into the shower. Valenka first appears when she is with Le Chiffre in the Bahamas, and she comes out of the sea in a luxurious blue swimsuit, and she has water streaming off her body.

The character is a supporting antagonist created specifically for EON Productions' 2006 James Bond film Casino Royale and was portrayed by Yugoslavian actress Ivana Miličević. Valenka is the fictional female companion of Quantum member and terrorist financier, Le Chiffre.

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